Inactive User
- #1
There are many excellent articles, guides and threads on aquatic plant fertilisers here at FishLore, on planted tank, thebarrreport.com, aquaticplantcentral.com and advancedplantedtank.com. The aI'm of this guide isn't to replace these resources, but to collate a comprehensive range of useful information in a way that's accessible for beginners; to cover the most popular methods for dosing ferts; and to address some common aspects of fert use that aren't immediately apparent.
Contents:
All plants require macronutrients (often called macros or NPK) in significant amounts, and these include nitrogen (N), phosphorus (P) and potassium (K).
Both nitrogen (in the form of nitrate NO3) and phosphorus (in the form of phosphate PO4) occur within aquariums as a result of the nitrogen cycle and the decomposition of excess fish food. Likewise, potassium is often found in trace quantities in tap water.
In addition, plants require micronutrients (sometimes referred to as micros and/or trace elements) in lesser amounts. These include iron, magnesium, calcium, sulfur, copper and several other elements. Many of these are found in tap water.
Carbon is sometimes considered a macronutrient as plants typically comprise up to 60-70% carbon. However, in planted tank fert dosing, sources of carbon are in most cases not listed as ferts because its main source is in the form carbon dioxide (CO2). Some products, including Excel and Metricide 14, can be dosed to supply carbon intermediaries. This is are examined in more detail in section 12.
2. Choosing a fert dosing method
There are a number of informal and formalised methods of dosing ferts, including (but not limited to):
For a beginner all of the above methods work well and can provide the necessary footing to become acquainted with ferts and other aspects of planted tanks. Because the input ferts are largely the same across EI and PPS (and any additional ferts can often be purchased affordably), switching between methods is simple if one should choose to do so in the future.
It is important to note, at this stage, that both EI and PPS rely on a well planted tank with sufficient plant biomass: simply having one Cryptocoryne and a few patches of Taxiphyllum barbierI 'Java moss' isn't likely to work well. A very lightly planted tank is better served by the conservative use of an all-in-one fert (see section 3 directly below).
3. All-in-one ferts
There are several aquarium-specific all-in-one ferts available which combine both macros and micros in a single mix. Most (if not all) are in the form of a liquid solution that is added directly to the tank's water column.
Many of these products are very dilute, and the bulk of the fert is simply a water solvent to the effect that one is mostly paying for water when purchasing these products. In addition, many contain little (if any) nitrogen or phosphorus based on the assumption that the aquarist's tank has a sufficient bioload such that nitrate and phosphates need not be dosed. This may not be the case for every tank, and many planted tanks typically have a low bioload due to aquascaping requirements.
The most useful all-in-one fert is NilocG Thrive, which is both comprehensive (all macros and micros) and concentrated. Thrive has a guaranteed analysis for its chemical composition and moreover, the fert's proportion of nutrients and recommend doses are structured according to the requirements of the Estimative Index (EI) method of dosing. Few competitor products offer a comprehensive listing of the solute nutrients in the fert.
The advantage in using a product like Thrive is that it is (1) easy to understand; and (2) easy to use, both of which are useful for beginners. It is particularly useful for very lightly planted tanks where using either EI or PPS may cause issues.
The disadvantage is that it's (1) unable to increase the dose of an individual nutrient in response to a particular deficiency; and (2) less cost-effective compared to using separate dry chemical fertilisers (which are often called dry ferts).
One caveat in using Thrive is that because of high fert concentration, it isn't especially best practice to follow the dosing instructions if your tank is very lighted planted as the recommend doses and frequency of dosing are structured according to high light, CO2-injected, well planted tanks with a low bioload. In moderately planted tanks with low light and no CO2 injection, it's better to use 1/2 of the recommended dose (1 pump per 20 gallons instead of 1 pump per 10 gallons) once a week (instead of 2-3 times a week). For very lightly planted tanks, it is recommended to use 1/2 of the recommended dose once every 1-2 weeks.
4. Estimative Index (EI)
The Estimative Index (EI) method of fert dosing was developed by Tom Barr, a noted planted tank expert who frequently contributes to the community at planted tank and thebarrreport.com.
The underlying principle of the EI method is the non-limitation of nutrients: all nutrients are dosed in excess to prevent a deficiency occurring for any given nutrient. Excess nutrients are removed through regular water changes. This is coupled with adequate lighting and sufficient CO2.
1. Potassium nitrate (KNO3)
2. Monopotassium phosphate (KH2PO4)
3. A micro fert mix, such as Plantex CSM+B or Flourish
4. Potassium sulphate (K2SO4) (optional)
Dosing K2SO4 is optional, as both KNO3 and KH2PO4 will generally supply adequate amounts of potassium when dosed according to recommended quantities for nitrate and phosphate.
On some occasions, when a tank's nitrate and/or phosphate levels are in excess without ferts (due to an elevated bioload and/or high feeding frequency), neither KNO3 or KH2PO4 are necessary. In which case, K2SO4 can be dosed separately as a potassium fert. K2SO4 can also be used with KNO3 and KH2PO4 in the case that potassium deficiency is observed in plants.
In addition, many planted tank aquarists dose an additional iron fert separately from their micro fert mix. This is discussed separately in section 7.
The following are the nutrient ppm targets for a high light tank injected with 25-35 ppm CO2 (often referred to as a high tech tank):
NO3: 5-30 ppm
PO4: 1-3 ppm
K: 10-30 ppm
Fe: 0.2-0.5 ppm
These targets are offered as a guide and the majority of people will adjust their individual fert doses in response to observations of plant growth. The adjustability of EI is important as no two tanks are alike in their nutrient uptake. As example, because of the density of fast-growing, stem plants in my planted tank, I routinely dose 4-5 ppm of PO4.
In order to reach the lower threshold of these targets, the following doses are required per 5 gallons:
KNO3: 154.67 mg (5 ppm NO3 and 3.15 ppm K)
KH2PO4: 137.22 mg (1 ppm PO4 and 0.46 ppm K)
Plantex CSM+B: 58 mg (0.2 ppm Fe) or Flourish : 1.2 ml (o.2 ppm Fe)
5. EI for low tech tanks
Low tech tanks are generally those that have low lighting and are not injected with CO2 (sometimes Excel or Metricide 14 may be used as a carbon supplement). The recommended fert doses listed above for high tech tanks can be adjusted for these low tech environments.
Rather than dosing 100% of the recommended dose three times a week, instead dose 50% of the recommended dose once a week. Instead of 50% water weekly water changes, opt for 10-25% weekly or fortnightly.
Over time, in response to plant growth, dosing may be increased from 50% to 100% of the recommended dose while maintaining the once per week dose frequency). If either Excel or Metricide is used daily, then one may dose immediately begin to dose 100% of the recommended doses once per week.
6. Perpetual Preservation System Pro (PPS-Pro)
To be updated.
7. Iron ferts
The iron present in micro ferts is generally chelated. That is, the iron is bound to chelating agents in order: (1) to improve its solubility in water; (2) to improve its biological availability to plants; and (3) to reduce the reactivity of iron to other elements/compounds in the water column (typically phosphate) which causes it to oxidise or precipitate into a form (such as ferrous phosphate) that is biologically unavailable to plants.
Chelating agents include the compounds EDTA, DTPA and EDDHA. The main distinction in use for planted tank aquarists is the stability of chelating agents at different pH levels. All iron chelates are stable at different pH ranges, with increasing alkalinity causing the iron to dissociate from the chelating agent and then becoming unavailable for plant uptake.
The following is an approximate comparison of the percentage of iron that remains chelated at different pH levels with different chelating agents:
EDTA iron chelate:
6.0 pH, 100% of iron chelated
6.5, 50%
7.0, 10%
7.5, 5%
DTPA iron chelate:
7.0 pH, 100% of iron chelated
7.5, 50%
8.0, 30%
EDDHA iron chelate:
11.0 pH, 100% of iron chelated
The iron present in Plantex CSM+B is chelated with EDTA. For those tanks where the pH is regularly at or above 7.0 pH, DTPA iron chelate is generally required to supplement Plantex CSM+B. Some aquarists routinely dose two or three times the recommended dose of Plantex CSM+B if their pH is at or slightly above 6.5 pH in order to provide sufficient iron. However, it is not recommended to dose Plantex CSM+B in proportions higher than this as there is vague anecdotal evidence that sufficient excess concentrations of other trace elements can cause toxicity issues. In addition, it isn't a particularly cost effective practice.
In general, few micro ferts contain DTPA iron chelate, so it will often need to be purchased and dosed separately. In addition, while EDDHA is most stable at the widest range of pH, it is not recommended for use in planted tanks due to its cost and tendency to stain tank water.
It is important to note that the iron in Flourish (and in Flourish Iron) is in the form of ferrous gluconate. While it is highly available for uptake by plants, it is also highly unstable and will generally become less available for plant uptake within 24 hours. Because of this, ferrous gluconate-based ferts need to be dosed daily. As with Plantex CSM+B, it is not recommended to dose Flourish daily due to vague anecdotal evidence regarding toxicity of other trace elements at excess concentrations (it also isn't a cost effective practice). Instead, it is recommended to use either Flourish Iron or EDTA/DTPA iron chelate (depending on tank pH).
Contents:
- Macronutrients and micronutrients
- Choosing a fert dosing method
- All-in-one ferts
- Estimative Index (EI)
- EI for low tech tanks
- Perpetual Preservation System (PPS-Pro)
- Iron ferts
- Flourish macro ferts
- Fert dosing calculators
- DIY dosing calculations
- DIY fert solutions
- Carbon intermediaries
- Substrates and substrate fertilisation
- Example of fert dosing regimens
All plants require macronutrients (often called macros or NPK) in significant amounts, and these include nitrogen (N), phosphorus (P) and potassium (K).
Both nitrogen (in the form of nitrate NO3) and phosphorus (in the form of phosphate PO4) occur within aquariums as a result of the nitrogen cycle and the decomposition of excess fish food. Likewise, potassium is often found in trace quantities in tap water.
In addition, plants require micronutrients (sometimes referred to as micros and/or trace elements) in lesser amounts. These include iron, magnesium, calcium, sulfur, copper and several other elements. Many of these are found in tap water.
Even though many of these nutrients (both macro and micro) are present in aquariums as a result of using tap water and other chemical processes, usually it is the case that most of these are not found in significant quantities to assure good plant growth. In the vast majority of tanks, dosing fertilisers (commonly abbreviated as ferts) is necessary.Note: The categorisation of nutrients as either a macro or a micro sometimes varies. For example, some resources consider magnesium, calcium and sulfate macros.
Carbon is sometimes considered a macronutrient as plants typically comprise up to 60-70% carbon. However, in planted tank fert dosing, sources of carbon are in most cases not listed as ferts because its main source is in the form carbon dioxide (CO2). Some products, including Excel and Metricide 14, can be dosed to supply carbon intermediaries. This is are examined in more detail in section 12.
2. Choosing a fert dosing method
There are a number of informal and formalised methods of dosing ferts, including (but not limited to):
- All-in-one ferts
- Estimative Index (EI)
- Perpetual Preservation System (PPS)
The difference between these methods is related to the input ferts (whether it is a premixed solution or a dry fertiliser compound); how much of each fert to dose; and how often ferts are to be dosed. Because of these differences, choosing between one of these methods for a beginner can be a bewildering decision. This is especially the case when trying to decide between a nutrient rich method such as the EI method compared to a nutrient lean method such as PPS.Note: These are not the only methods available, but these are the most prominent in North America and other English-speaking countries (Australia, New Zealand, etc.). Other methods, such as ADA, can be found commonly in Europe and Asia.
These and other differences arise mostly because of competing (and in some cases, mutually exclusive) understandings of plant biology and how nutrients are best apportioned in aquariums to elicit good plant worth while minimising undesirable effects (such as algae). This guide won't seek to explain the differences in depth due to the relative complexity (and contested nature) of the underlying theory. Aquarists are instead encouraged to read the 'Which Dosing Approach?' article at advancedplantedtank.com as an example of one way to differentiate across methods of dosing. In addition, planted tank has historically been dominated by EI dosing, while aquaticplantcentral.com has a higher proportion of PPS users.Note: Because most all-in-one ferts are quite dilute and their dosing recommendations very conservative, most would be considered nutrient lean. NilocG Thrive is one exception because of its concentrated formulation.
For a beginner all of the above methods work well and can provide the necessary footing to become acquainted with ferts and other aspects of planted tanks. Because the input ferts are largely the same across EI and PPS (and any additional ferts can often be purchased affordably), switching between methods is simple if one should choose to do so in the future.
It is important to note, at this stage, that both EI and PPS rely on a well planted tank with sufficient plant biomass: simply having one Cryptocoryne and a few patches of Taxiphyllum barbierI 'Java moss' isn't likely to work well. A very lightly planted tank is better served by the conservative use of an all-in-one fert (see section 3 directly below).
3. All-in-one ferts
There are several aquarium-specific all-in-one ferts available which combine both macros and micros in a single mix. Most (if not all) are in the form of a liquid solution that is added directly to the tank's water column.
Many of these products are very dilute, and the bulk of the fert is simply a water solvent to the effect that one is mostly paying for water when purchasing these products. In addition, many contain little (if any) nitrogen or phosphorus based on the assumption that the aquarist's tank has a sufficient bioload such that nitrate and phosphates need not be dosed. This may not be the case for every tank, and many planted tanks typically have a low bioload due to aquascaping requirements.
The most useful all-in-one fert is NilocG Thrive, which is both comprehensive (all macros and micros) and concentrated. Thrive has a guaranteed analysis for its chemical composition and moreover, the fert's proportion of nutrients and recommend doses are structured according to the requirements of the Estimative Index (EI) method of dosing. Few competitor products offer a comprehensive listing of the solute nutrients in the fert.
The advantage in using a product like Thrive is that it is (1) easy to understand; and (2) easy to use, both of which are useful for beginners. It is particularly useful for very lightly planted tanks where using either EI or PPS may cause issues.
The disadvantage is that it's (1) unable to increase the dose of an individual nutrient in response to a particular deficiency; and (2) less cost-effective compared to using separate dry chemical fertilisers (which are often called dry ferts).
One caveat in using Thrive is that because of high fert concentration, it isn't especially best practice to follow the dosing instructions if your tank is very lighted planted as the recommend doses and frequency of dosing are structured according to high light, CO2-injected, well planted tanks with a low bioload. In moderately planted tanks with low light and no CO2 injection, it's better to use 1/2 of the recommended dose (1 pump per 20 gallons instead of 1 pump per 10 gallons) once a week (instead of 2-3 times a week). For very lightly planted tanks, it is recommended to use 1/2 of the recommended dose once every 1-2 weeks.
Note: Flourish is sometimes called Flourish Comprehensive to avoid confusion with other Flourish products. Despite its informal name, it is not a comprehensive, all-in-one fert. It has a distinct lack of macros and is best used as a micro fert. See this sticky thread by Mak for further information.
4. Estimative Index (EI)
The Estimative Index (EI) method of fert dosing was developed by Tom Barr, a noted planted tank expert who frequently contributes to the community at planted tank and thebarrreport.com.
The underlying principle of the EI method is the non-limitation of nutrients: all nutrients are dosed in excess to prevent a deficiency occurring for any given nutrient. Excess nutrients are removed through regular water changes. This is coupled with adequate lighting and sufficient CO2.
The EI method typically uses dry ferts, the primary compounds being:Note: Excess ferts (whether it is phosphate or another nutrient) will not cause algae issues in a well planted tank dosed with the EI method (or any other method, such as PPS).
It is the general consensus that algae growth in planted tanks is primarily due to poor plant growth and/or poor maintenance. An excess of dead/dying plant matter and a failure to undertake routine pruning/replanting/vacuuming causes an excess of carbohydrates and other organic compounds that triggers the growth of algae.
Combating algae is then a process of assuring good plant growth (either by sufficient ferts, lighting or CO2) and regular tank maintenance
1. Potassium nitrate (KNO3)
2. Monopotassium phosphate (KH2PO4)
3. A micro fert mix, such as Plantex CSM+B or Flourish
4. Potassium sulphate (K2SO4) (optional)
Dosing K2SO4 is optional, as both KNO3 and KH2PO4 will generally supply adequate amounts of potassium when dosed according to recommended quantities for nitrate and phosphate.
On some occasions, when a tank's nitrate and/or phosphate levels are in excess without ferts (due to an elevated bioload and/or high feeding frequency), neither KNO3 or KH2PO4 are necessary. In which case, K2SO4 can be dosed separately as a potassium fert. K2SO4 can also be used with KNO3 and KH2PO4 in the case that potassium deficiency is observed in plants.
In addition, many planted tank aquarists dose an additional iron fert separately from their micro fert mix. This is discussed separately in section 7.
The following are the nutrient ppm targets for a high light tank injected with 25-35 ppm CO2 (often referred to as a high tech tank):
NO3: 5-30 ppm
PO4: 1-3 ppm
K: 10-30 ppm
Fe: 0.2-0.5 ppm
These targets are offered as a guide and the majority of people will adjust their individual fert doses in response to observations of plant growth. The adjustability of EI is important as no two tanks are alike in their nutrient uptake. As example, because of the density of fast-growing, stem plants in my planted tank, I routinely dose 4-5 ppm of PO4.
In order to reach the lower threshold of these targets, the following doses are required per 5 gallons:
KNO3: 154.67 mg (5 ppm NO3 and 3.15 ppm K)
KH2PO4: 137.22 mg (1 ppm PO4 and 0.46 ppm K)
Plantex CSM+B: 58 mg (0.2 ppm Fe) or Flourish : 1.2 ml (o.2 ppm Fe)
Under a high tech tank environment, these quantities are dosed three times a week, with a 50% water change at the end of the week. Macros (KNO3 and KH2PO4) are dosed on alternate days and are dosed separately from micros (Plantex CSM+B or Flourish). For example, macros may be dosed on Monday, Wednesday and Friday; micros dosed on Tuesday, Thursday and Saturday; and a water change is completed on Sunday.Note: As iron is the micro required in the highest concentration, it is typically used as the benchmark for determining micro fert mix doses: it is assumed that other the other trace elements in the micro fert mix will be present in necessary amounts when adequate iron is dosed.
It is highly recommended to read section 7 regarding the use of iron ferts for more complete information about their use.Note: Micros and macros are dosed separately in order to limit the reaction between iron and phosphate. However, as concentrations of both nutrients in typical aquariums with EI dosing remain relatively low, the extent of precipitation into ferrous phosphate is generally minimal even if dosed together. As a point of comparison, iron and phosphates are dosed together daily under the PPS-Pro method.
5. EI for low tech tanks
Low tech tanks are generally those that have low lighting and are not injected with CO2 (sometimes Excel or Metricide 14 may be used as a carbon supplement). The recommended fert doses listed above for high tech tanks can be adjusted for these low tech environments.
Rather than dosing 100% of the recommended dose three times a week, instead dose 50% of the recommended dose once a week. Instead of 50% water weekly water changes, opt for 10-25% weekly or fortnightly.
Over time, in response to plant growth, dosing may be increased from 50% to 100% of the recommended dose while maintaining the once per week dose frequency). If either Excel or Metricide is used daily, then one may dose immediately begin to dose 100% of the recommended doses once per week.
6. Perpetual Preservation System Pro (PPS-Pro)
To be updated.
7. Iron ferts
The iron present in micro ferts is generally chelated. That is, the iron is bound to chelating agents in order: (1) to improve its solubility in water; (2) to improve its biological availability to plants; and (3) to reduce the reactivity of iron to other elements/compounds in the water column (typically phosphate) which causes it to oxidise or precipitate into a form (such as ferrous phosphate) that is biologically unavailable to plants.
Chelating agents include the compounds EDTA, DTPA and EDDHA. The main distinction in use for planted tank aquarists is the stability of chelating agents at different pH levels. All iron chelates are stable at different pH ranges, with increasing alkalinity causing the iron to dissociate from the chelating agent and then becoming unavailable for plant uptake.
The following is an approximate comparison of the percentage of iron that remains chelated at different pH levels with different chelating agents:
EDTA iron chelate:
6.0 pH, 100% of iron chelated
6.5, 50%
7.0, 10%
7.5, 5%
DTPA iron chelate:
7.0 pH, 100% of iron chelated
7.5, 50%
8.0, 30%
EDDHA iron chelate:
11.0 pH, 100% of iron chelated
The iron present in Plantex CSM+B is chelated with EDTA. For those tanks where the pH is regularly at or above 7.0 pH, DTPA iron chelate is generally required to supplement Plantex CSM+B. Some aquarists routinely dose two or three times the recommended dose of Plantex CSM+B if their pH is at or slightly above 6.5 pH in order to provide sufficient iron. However, it is not recommended to dose Plantex CSM+B in proportions higher than this as there is vague anecdotal evidence that sufficient excess concentrations of other trace elements can cause toxicity issues. In addition, it isn't a particularly cost effective practice.
In general, few micro ferts contain DTPA iron chelate, so it will often need to be purchased and dosed separately. In addition, while EDDHA is most stable at the widest range of pH, it is not recommended for use in planted tanks due to its cost and tendency to stain tank water.
It is important to note that the iron in Flourish (and in Flourish Iron) is in the form of ferrous gluconate. While it is highly available for uptake by plants, it is also highly unstable and will generally become less available for plant uptake within 24 hours. Because of this, ferrous gluconate-based ferts need to be dosed daily. As with Plantex CSM+B, it is not recommended to dose Flourish daily due to vague anecdotal evidence regarding toxicity of other trace elements at excess concentrations (it also isn't a cost effective practice). Instead, it is recommended to use either Flourish Iron or EDTA/DTPA iron chelate (depending on tank pH).