4-5 " is deep gravel. Depending on the size of gravel, may/may not have anaerobic acitivities. Unless deep sand bed (
DSB), doubt it. Look from underneath the tank, should see black area on bottom on sand. If new tank vacuumed regularly, very unlikely.
When you vacuum the gravel, do you see bubbles rising from gravel with funky (rotten egg; hydrogen sulfide, smell just like marsh in low tides) odor?
Dont have all the fact as far as age of tank since set up, amt of fish, etc? If small amt of NO3 is produced by tank, may be being utilized by algae or by water changes?