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Well you need to be worried about the tank and sump. Mainly the sump, because of gravity and siphons...thats where the water is going in a power failure. Should work with a switch but those could possibly fail.
I think the safer way would also to account for flooding beforehand. Don't count a 10gal as 10gals of water. Fill it 1/2-3/4 up with sump baffles installed so that when the power goes off, there is room for water to drain into the sump if none is getting pumped out. Should stop once water can't get into the overflow and finishes draining whats in the pipes.
Also drill a small hole or two in the return line underwater (1/2" or so?) so that when that hole breaks air, as the aquarium drains the siphon breaks on the return and water no longer drains out.
In a power failure your overflow and return lines are both dumping back into the tank because of the siphon, so account for that as well.
The switch should work with the power on, just giving you a few other things to think about as far as flooding goes.
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