I'd get the measurements on that tank, picture is decieving and tank looks smaller the 100gals.
If it is indeed a 100gal there are many options as far as fish and inverts go, to many to list. I'd browse some sites and see what catches your eye, then research that fish more. Inverts don't take much bioload and with 100gals you'd be able to have multipule shrimp/crabs.
As far as coral goes, once the tank is cycled you could add coral, not usually recommended as coral need and prefer a good established tank. However some of the easy stuff like Zoanthids, Palythoa, star polyps, and mushrooms would work well to start.
If you do indeed want to keep coral, make sure the fish you get are reef safe. Also keeping coral is going to run up the costs of the setup, lighting is key. And on a 100gal it can be pricey. Coral itself can be found pretty cheap, and its really not that hard to care for IMO. Just keep your water right and the coral will keep itself alive. As long as the water is good, the only thing coral needs is light to live.
FOWLR and FO tanks are called that for a reason. Usually the fish in these tanks are predetors and/or fish that much reef inhabitants (Inverts, other fish, coral). So you will be very limited as far as "other creatures" go.
Heaters, i prefer Visatherm Stealth heaters. Skimmers, there are quite a few good companies. On a tank this large a good
skimmer would be a good investment. They are expensive though. ATI (Bubble Master), Tunze, Reef Octopus, all are good. There are a few other brands out there.