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1) If you are going to run a skimmer on this tank, run it from day 1 (so...yes).
2) When I cycled my tanks, the ammonia spiked off the chart, which tops out at 8.
3) Yes, some. If you will be keeping calcifying corals, however, you might want to consider using Reef Crystals instead. Reef Crystals are by the same company and is essentially the same "base" mix as Instant Ocean, but with higher levels of elements that get used up in a reef aquarium. Including calcium.
4) Sounds good.
There are no stupid questions!
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