The only real tank mates for
goldfish other than goldfish are Garra Pingu Pingu which can be hard to find. I have had success with Otos, but most people on here would advise against using them for
algae control.
Plecos are tropical and need warmer water than a goldfish which can survive almost freezing temperatures. The goldfish is also a huge waste producer and makes the water chemistry harder on other fish.
Also, the Nitrite and ammonia readings are concerning. You should have no Nitrite or ammonia at all in a tank. This means the tank is not cycled and the fish are swimming in poisonous waste byproducts. Having any readings of those two waste products is a sign your tank isnt cycled.