I wouldn't but anything against the glass for several reasons. You don't want to put extra weight on the glass that could strain the seals and cause a leak. If the rocks happen to fall they could easily break the tank. Also you wouldn't be able to clean behind there and that could cause high nitrates which isn't good for your fish. Also most fish like to swim in and out of things having it right against the glass would prevent them from being able to do that.
Just saw your talking about
live rock..lol..That might change the swimming in and out of thing depending on how you have them stacked but the rest still applies
