I don't believe there's any need to compensate just because your lighted hours aren't consecutive. I run my lights from 9am-1pm and 4pm-10pm with good growth and no adverse affects.
If you want to see better growth, get rid of the actinic bulb. They're good for marine setups/coral, but not so great for freshwater plants, and the same goes for the 50/50 lights. You'd do much better with a 6700K,
GE 9325K (my personal favorite, and compatible with the Coralife fixtures), or 10000K bulb.
Another note is carbon. With 260 potential watts of light over 90 gallons, you're going to need
some sort of carbon supplementation. Pressurized CO2 would be best, but Flourish Excel can work if you're lucky. I have 40W less than you do but better reflectors, so I'd say we're probably about even on lighting, and I'm contemplating which bank to rob to afford a CO2 setup

Excel is doing OK for me, but I know the tank could do much better.
High lighting also introduces a need for fertilization. Are you doing anything on that front?