Well, I turn on my aquarium light for decoration and the beauty of it. I don't mostly turn it on in the morning for it's a waste of electricity when there is natural light in the day. Unless, your aquarium is in a darkly lit room, then it is fine. But having natural light and aquarium light together isn't really good from what I heard.
But when you DO turn on the aquarium light, make it constant and at the same time everyday! For instance, if you turn it on at 11am, and turn it off at 11pm, make sure you do that everyday at the same time. Try keeping it a schedule, so your fish will be familiar with the lights so they don't get stressed out like what lew said.
Good luck!
