If there's any chance there have been chemicals sprayed around the base of the house where these rocks have been dug up I personally wouldn't use them.
How much limestone you use in the tank, how often you do water changes, what size water changes you do would affect whether/how much the limestone will affect your pH.
If you are doing regular water changes and use just a couple of limestone rocks you won't notice a significant difference in ph.
I have Carib sea's sahara sand(cichlid Sand) and Texas Holey Rock in my Multi tank but I do 25 - 50% water changes on that tank every week. The ph is the same as it is in all the other tanks. The reason being the rock dissolves so slowly that when doing water changes that little bit is removed. This is how it works for me

If you decide the rocks would be safe to use a good scrubbing to remove dirt and a good boiling will make it safe for your tank without chemicals. If you boil them let them cool gradually. Cooling in cold water can cause them to explode.
Hope that helps.
Carol