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Unless you have more tanks than what's in your profile, I'm not sure any of your fish are big enough to eat earthworms. Bloodworms, perhaps. (Though, I suppose, if you cleaned them off and rendered them into little bits, earthworms would work. Wouldn't be live food anymore, though).
For the second question, partly true. The vinegar test just means the rock won't raise the pH of the water. It doesn't test for pollutants, metals, or other things that could leach into your water. If you see anything metallic in a rock, it's not acceptable (you might want to break a bit with a hammer to check this). If it came from a polluted area, you probably don't want to mess with it, either.
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