Hot thread! too bad I missed it from day one!
In the CO2

H "heated" theme, both are correlated, but other variables play a role here too. (you take pH and KH measures and you can figure out the level of dissolved CO2 in your tank; temperature, as we use it in fishkeeping is insignificant).
CO2 will absolutely bring your pH down, just a matter of time (a matter of both,
DKH and CO2 difussion, actually) of when it happens and if it could or not be dangerous to pH stability (be careful if dKH goes below 2!).
As for addressing the issue in this thread, Ok... this is my little grain of sand, based on my experience (limited) and knowledge (also limited):
Rule of thumb #1: If your fish can thrive in your actual readings of pH, let it be. A stable pH is a must in fishkeeping, to the point that if you risk that, your tank will collapse (pH crash) and no one will survive (e.g. pH 4.0). pH ranges offered from the natural environment or niche of species is critical only for particularly delicate fish (e.g. Discus) or specimens that are caught in the wild (not breed in aquaculture tanks) and therefore you should aim at matching those parameters to the best of your abilities. Otherwise, don't worry too much. My experience: Green and Gold Severums from the wild will likely suffer at ph7.6 -my tank- but the ones I bought at the LFSs where kept at 7.4 and 7.6, so I let it be for the time being, until I intend to breed them, and then again, they might breed without my intervention.
Rule of thumb #2: Whenever possible, adjust pH without fish in the tank. That way no one gets hurt if a mistake is made -and mistake are prone in non-experienced fishkeepers as myself-, except, maybe, the colonies of beneficial bacteria. Then take your time acclimating your fish back to the tank.
Rule of thumb #3: If you must tamper pH wiht fish in the tank, there are safe ways to do it -tried and true,
but it's allways easier -and safer- to raise pH than lower it. In your case, if you need to bring it down, you need to log (register, record) info on the following:
GH, KH, pH, Temp. I am doing this right now, in my Angelfish tank.
Rule of thumb #4: Water color is optional. Use and replace regularly activated charcoal media if you don't want your water to be tanned -with tannins from drifwood, peat. This will keep your water cristal clear and you will not lose the benefit of the organic compounds that remove carbonates in the water. Or remove it if you want to recreate Amazon bio-type (e.g. for Discus, Angelfish, Oscars), the tea-coloured water looks great to me and some fish love it, but other hate it (e.g. African Cichlids).
To lower pH:
1) Take a sample of your tap water and tank water, place them in two separate shallow plates, leave them sit overnight, measure pH in early morning hours. (Dissolved Oxygen will lead to false high readings of pH). Your measures of GH and KH will not be affected by this, so you can measure them right away: to avoid mistakes, take two or three measures and use 10ml (instead of 5), add each drop and mix, take your time, count the number of drops it takes for the colour to change, divide it by two, and there you have your dGH and dKH. Multiply those values by 17.9 and you have the
PPM of each. Log this values for future reference.
2) If your water is extremely hard, you will need to dilute it with
reverse osmosis (
RO) treated drinking water (do not use distilled water). Note that purchasing, installing and using a RO unit is expensive, and for the most part not cost effective in freshwater fishkeeping. You must be careful if you are doing this with fish in your tank. Use peat media sold for aquarium use, cheaper peat, sold for gardening can contain dangerous chemicals for fish.
This what I have done in my Angelfish tank with fish in it (a 29gal tall tank), a work in progress:
Before adjusting pH: Temp 27-28C (midnite-noon); pH 7.7-7.8 (midnite-noon); GH 16 dGH; KH 11dKH.
First I tried using peat extract from a product called Blackwater Extract from Tetra (TetraAqua division). It didn't worked at all. I used it for two weeks, adding at partial water changes, no results. Then I did a 50% water change (almost 10gal of water) using 3gal of RO treated drinking water. pH remained the same, but kdH dropped a bit to 9.5. After two weeks, I used 5gal of RO treated drinking water, pH remained the same, kdH stayed allmost identical, at 9 dKH. So I added Fluval Peat Fiber (out of market, but available down here) being conservative: It comes in 70g packs, so I used a bit under 1/3, aiming at 20 to 25g. I flushed it in tank water, placed it in the HOB in this order -bottom to top: Activated Charcoal, Peat Fiber mixed with Ceramic Media, Sponges (I allways use extra sponges). I used RO treated drinking water in a 50:50 solution with treated tap water for 3 weeks. At week 4, I had to stop doing that since KH went down to 2.5, still safe, but disaster can happen if it goes below 2.0.
Last week readings:
pH 7.1-7.2 (midnite-noon), GH 7dH; KH 2.5dKH. I decided to remove some of the peat, and used treated tap water. Also kept at hand crushed corals, just in case a reading of 2.0dKH was obtained.
Actual readings (yesterday):
Temp 27-28C, pH 7.1-7.2 (midnite-noon), GH 7dH; KH 3.0dKH,
ammonia 0, Nitrites 0, Nitrates <10ppm.
I will wait until KdH raise to at least 4.0 before using a cheap DIY CO2 system. For the sake of the fish. It has taken me over 4 weeks to go from 7.7 to 7.2. I will most likely hit 6.8 (my target) with minimal levels of dissolved CO2 -airstone difussor might do it.
Sidenote: A drawback is that peat media should be replaced every 4 to 5 weeks. And
Activated Charcoal replaced every 3 weeks at the most. However, if a bag of 70g lasts
for 3 or 4 months, I would say it is cost-effective. Maybe at that point, blackwater extracts, that contain peat extract, would do the work wonderfully.
Another Sidenote: Keeping crushed corals (sold as substrate at the saltwater section of the
LFS) at hand for inmediate use will stop pH from going down, indeed, it will put the "get the pH down project" in pause, but will give your fish room for surviving.
Hope this is helpful for you
Pepe
Santo Domingo