Hello and welcome to fishlore.

cory cats are so much fun to have in a tank as you probably already know. As far as why your guys are hanging out at the top of the tank Im not sure. You say that the the water perimeters are good, but after only one week of set up your tank has not gone through the
nitrogen cycle yet. What are your readings exactly? Corys are very sensitive fish and should only be brought into a well established fish tank that has gone through the nitrogen cycle. What other fish do you have in the tank? Is it a planted tank?

~ kate