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It depends on the fish. Mollies, as fishgal said, actually like some salt. Black lyretails prefer water that is closer to true saltwater than true freshwater. Guppies, I believe, prefer a small amount of salt. Basically, fish that, in the wild, live in brackish water would prefer brackish water in their tank.
On the other hand, scale-less fish such as cories and plecos are stressed by salt. My guess is that the salt draws water out through their skin, as there are no scales in the way to slow osmosis down. In most community tanks, don't put any salt in. If you've got a tank full of brackish fish, on the other hand (like my mollies and Amano shrimp), they'd probably love some salt in the water.
If you do decide to make your tank brackish, do it slowly, over the course of days, and use normal aquarium salt, not the therapeutic stuff. The therapeutic stuff is made for short-term use.
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