Usually in a planted tank it isn't the substrate that will cause problems. IF it is deep enough, plants can get most of their nutrients out of the fish waste, and you can "feed" them, the gravel just gives your plants a place to anchor and put out roots.
Some materials do add minerals that plants can use, things like eco-complete, which also is infused with bacteria to help jump-start your nitrogen cycle. This is especially valuable in planted tanks that utilize high light and CO2. The fast growth requires higher, more available levels of nutrients, but for most tanks with a moderate plant load, gravel 2-3"thick and plant fertilizer tabs are enough.
Research the plants you have, or want to get at
www.plantgeek.net for their light requirements. Light, and not substrate will have the biggest impact on what plants you can successfully grow in your tank.
IF you want to add or replace your substrate, it will entail removing the fish to a bucket (heater & air can be used), dumping most of the water and re-decorating. It won't help your plants though, if your lighting isn't strong enough. Good Luck
